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[5], Selenium forms several allotropes that interconvert with temperature changes, depending somewhat on the rate of temperature change. Elements are organised into blocks by the orbital type in which the outer electrons are found. ), woody asters (Xylorhiza sp. Although trace amounts of selenium are necessary for cellular function in many animals, including humans, both elemental selenium and (especially) selenium salts are toxic in even small doses, causing selenosis. Most of the worlds selenium is obtained from the anode muds produced during the electrolytic refining of copper. Low = substitution is possible with little or no economic and/or performance impact. Deiodinases are able to extract electrons from iodides, and iodides from iodothyronines. The number of atoms of the element per 1 million atoms of the Earths crust. Found inside Page xi for antimony 203 10.3 Selenium 204 10.3.1 Chemical and physical properties of selenium 205 10.3.2 Production and uses of selenium 206 10.3.3 Selenium in Marston Bogert first produced aromatic polyimides in 1908 . [137] Neonate ruminants at risk of white muscle disease may be administered both selenium and vitamin E by injection; some of the WMD myopathies respond only to selenium, some only to vitamin E, and some to either. The percentage of an element produced in the top producing country. The sulfoxide in sulfur chemistry is represented in selenium chemistry by the selenoxides (formula RSe(O)R), which are intermediates in organic synthesis, as illustrated by the selenoxide elimination reaction. These include silver selenite (Ag2SeO3) and sodium selenite (Na2SeO3). various regions within North America) where low selenium soil levels lead to low concentrations in the plants, some animal species may be deficient unless selenium is supplemented with diet or injection. [64], Amorphous selenium (-Se) thin films have found application as photoconductors in flat panel x-ray detectors. Selenium requirements in plants differ by species, with some plants requiring relatively large amounts and others apparently requiring none. Selenium is incorporated into several prokaryotic selenoprotein families in bacteria, archaea, and eukaryotes as selenocysteine,[96] where selenoprotein peroxiredoxins protect bacterial and eukaryotic cells against oxidative damage. [53][54], About 2,000tonnes of selenium were produced in 2011 worldwide, mostly in Germany (650t), Japan (630t), Belgium (200t), and Russia (140t), and the total reserves were estimated at 93,000tonnes. Michiaki Yamashita, Shintaro Imamura, Md. This is approximately the sum of the number of protons and neutrons in the nucleus. These values were determined using several different methods. Found inside Page 153Selenium , The Physical Properties of , P. J. Nicholson , 3 , 1 . Selenium Resistance , The Time Factor in , G. E. Grantham , 4 , 259 . Selenium , The It is defined as the equilibrium pressure exerted by the gas produced above a substance in a closed system. The selenide dianion Se2 forms a variety of compounds, including the minerals from which selenium is obtained commercially. We hope that you enjoy your visit to this Site. Selenium is an essential trace element for some species, including humans. Selenium dichloride is an important reagent in the preparation of selenium compounds (e.g. Half of the distance between two unbonded atoms of the same element when the electrostatic forces are balanced. Adult fish may appear healthy despite their inability to produce viable offspring. What are properties of find_element_by_class_name in selenium python? Selenium also has numerous unstable synthetic isotopes ranging from 64Se to 95Se; the most stable are 75Se with a half-life of 119.78days and 72Se with a half-life of 8.4days. This smell was not typical of arsenic, but a similar odor was known from tellurium compounds. There have been numerous studies, none of them very conclusive, about the possible role of selenium in cancer prevention, and in increasing the efficacy of chemotherapy. Selenium forms two oxides: selenium dioxide (SeO2) and selenium trioxide (SeO3). So it can clear up an itchy scalp but it might make you stink in the process. Found inside Page 311Chapter 12 Cubic Cadmium Selenide ( C - CdSe ) 12.1 STRUCTURAL PROPERTIES 12.1.1 12.1.2 Isotopic abundance in percent for cadmium and selenium ( 1.2 ) . These blocks are named for the characteristic spectra they produce: sharp (s), principal (p), diffuse (d), and fundamental (f). Selenium often causes a malformed fish fetus which may have problems feeding or respiring; distortion of the fins or spine is also common. Relative atomic mass Medium = substitution is possible but there may be an economic and/or performance impact, Low = substitution is possible with little or no economic and/or performance impact, If you wish to use the Images in a manner not permitted by these terms and conditions please contact the Publishing Services Department. Elements are organised into blocks by the orbital type in which the outer electrons are found. Hence, Berzelius's first letter to Alexander Marcet stated that this was a tellurium compound. Group Found inside Page iIt has a role in making antioxidant enzymes and a particular role in the functioning of the thyroid gland. This volume examines the chemical activity of selenium and its functional health effects eg towards cancers, in the heart and brain. Selenium intensifies and extends the tonal range of black-and-white photographic images and improves the permanence of prints. A measure of how difficult it is to compress a substance. At the Kesterson National Wildlife Refuge in California, thousands of fish and waterbirds were poisoned by selenium in agricultural irrigation drainage. Found inside Page 83In In-In: 3-15 Im-In: 3-16 Aylbyl (Ga, In)2(Se, Te)3 In: 346 Se; Se: 346 In (Ga, Im): 4(Se, Te) 2:57-2-60 in In2 Sea 2-58 in In2Sea In: 0-95 In Se, The RSC has been granted the sole and exclusive right and licence to produce, publish and further license the Images. [124], The Occupational Safety and Health Administration (OSHA) has set the legal limit (permissible exposure limit) for selenium in the workplace at 0.2mg/m3 over an 8-hour workday. Describes the chemical elements with similar physical and molecular properties as oxygen, including how they combine with other elements and each other, and where they can be found in everyday objects. It is given by the ratio of the pressure on a body to the fractional decrease in volume. Nor shall the RSC be in any event liable for any damage to your computer equipment or software which may occur on account of your access to or use of the Site, or your downloading of materials, data, text, software, or images from the Site, whether caused by a virus, bug or otherwise. [82] There are, however, a few species that have been seen to survive these events and tolerate the increased selenium. Atoms of the same element with different numbers of neutrons. [111] This 400g Tolerable Upper Intake Level is based primarily on a 1986 study of five Chinese patients who exhibited overt signs of selenosis and a follow up study on the same five people in 1992. Copper indium gallium selenide is a material used in solar cells. [60][61] Selenium produces the same machinability improvement in copper alloys.[62]. It is recommended that a water concentration of 2g Se/L be considered highly hazardous to sensitive fish and aquatic birds. But for horses, with their more limited diet, selenium deficiency is common and often corrected with dietary supplements. )[108], Selenium may be measured in blood, plasma, serum, or urine to monitor excessive environmental or occupational exposure, to confirm a diagnosis of poisoning in hospitalized victims, or investigate a suspected case of fatal overdose. Where more than one isotope exists, the value given is the abundance weighted average. Analysis of blood levels of inorganic compounds in the supplement indicated the selenium concentrations were 10 to 15 times higher than normal in the blood samples, and 15 to 20 times higher than normal in the liver samples. He also noted that it was like sulfur and indeed had properties intermediate between sulfur and tellurium. The element is named after Selene, the Greek goddess of the moon. Some analytical techniques are capable of distinguishing organic from inorganic forms of the element. Native (i.e., elemental) selenium is a rare mineral, which does not usually form good crystals, but, when it does, they are steep rhombohedra or tiny acicular (hair-like) crystals. Selenium primarily occurs in vivo as selenocompounds, mostly selenoproteins such as glutathione peroxidase and thioredoxin reductase (enzymes responsible for detoxification). metallic and non-metallic forms. The boron mineral ulexite exhibits natural fiberoptic properties. Selenium trioxide. Selenium is toxic to the scalp fungus that causes dandruff so it is used in some anti-dandruff shampoos. But it's not all bad news. Primary minerals include argyrodite (from which it was first isolated), germanite, renierite, and canfieldite, all of them rare; only germanite and renierite have been used as commercial sources for the element. Atomic number In June 2015, the US Food and Drug Administration (FDA) published its final rule establishing the requirement of minimum and maximum levels of selenium in infant formula. Subsequently, selenium and various selenium compounds have been used in a variety of photoconductor and photovoltaic applications. In no event shall the RSC be liable for any damages including, without limitation, indirect or consequential damages, or any damages whatsoever arising from use or loss of use, data or profits, whether in action of contract, negligence or other tortious action, arising out of or in connection with the use of the material available from this Site. For salmon, the optimal concentration of selenium is about 1 microgram selenium per gram of whole body weight. It can also convert AC electricity to DC electricity, so is extensively used in rectifiers. [80] Fish are a major source of protein for humans. The lithiumselenium (LiSe) battery is one of the most promising systems for energy storage in the family of lithium batteries. selenium, vanadium, magnesium, copper, and zinc, may have been lacking in some terrestrial mineral-deficient areas. Selenium is listed as an ingredient in many multivitamins and other dietary supplements, as well as in infant formula, and is a component of the antioxidant enzymes glutathione peroxidase and thioredoxin reductase (which indirectly reduce certain oxidized molecules in animals and some plants) as well as in three deiodinase enzymes. 1. [65] These detectors use amorphous selenium to capture and convert incident x-ray photons directly into electric charge.[66]. Also, people dependent on food grown from selenium-deficient soil are at risk. In these compounds, selenium plays a role analogous to that of sulfur. The recoding mechanism was worked out first in bacteria and then in mammals (see SECIS element).[40]. In this tutorial, I will discuss 25 routinely used Selenium WebDriver commands along with their concerned This is followed by separate chapters on the environmental aspects of Se, including its presence in mineral deposits, soils, water, air, and uptake by plants; Se contents of human foods and animal feedstuffs; biological utilization of It is defined as being the charge that an atom would have if all bonds were ionic. Selenium has the electronic band structure of a semiconductor and retains its semiconducting properties in liquid form. ), and false goldenweed (Oonopsis sp. Join the community of over 1 million readers. A semi-metal that can exist in two forms: as a silvery metal or as a red powder. Non-metals are Selenium-specific supplements typically contain either 100 or 200g/serving. Selenium came to medical notice later because of its toxicity to industrial workers. Selenium rectifiers were first used in 1933. Reproduction of mallard ducks is impaired at dietary concentrations of 7ug Se/L. Because of its similarity to tellurium, named for the Earth, Berzelius named the new element after the Moon.[26][27]. Now customize the name of a clipboard to store your clips. For this purpose, various selenite and selenate salts are added. [49][50] Since its invention, solvent extraction and electrowinning (SX/EW) production of copper produces an increasing share of the worldwide copper supply. Density (g cm3) Other problems include degeneration of liver tissue, swelling around the heart, damaged egg follicles in ovaries, cataracts, and accumulation of fluid in the body cavity and head. [48], Selenium is most commonly produced from selenide in many sulfide ores, such as those of copper, nickel, or lead. Alone or in combination with Vitamin E, selenocompounds act as antioxidants. For more information on the Visual Elements image see the Uses and properties section below. The name is derived from 'selene', the Greek name for the Moon. The temperature at which the solidliquid phase change occurs. A percentile rank for the political stability of the country with the largest reserves, derived from World Bank governance indicators. The demand for selenium by the electronics industry is declining. These data exclude two major producers: the United States and China. nitrogen, phosphorus, sulfur and selenium. [12] Isotopes lighter than the stable isotopes primarily undergo beta plus decay to isotopes of arsenic, and isotopes heavier than the stable isotopes undergo beta minus decay to isotopes of bromine, with some minor neutron emission branches in the heaviest known isotopes. Berzelius and Gahn wanted to use the pyrite and they also observed that the red precipitate gave off a smell like horseradish when burned. To learn more about the physical & chemical properties of helium and its uses visit BYJU'S. [clarification needed]. Most of my fellow automation testers prefer the combination of WebDriver with Java. Selenium was discovered by Jns Jacob Berzelius at Stockholm in 1817. Covalent radiusHalf of the distance between two atoms within a single covalent bond. However, the lack of tellurium compounds in the Falun Mine minerals eventually led Berzelius to reanalyze the red precipitate, and in 1818 he wrote a second letter to Marcet describing a newly found element similar to sulfur and tellurium. Semiconducting properties in liquid form of compounds, including humans, iron, copper, colorless LiquidGas phase change occurs might make you stink in the photophone developed by Werner Siemens in the regions e.g. Of arsenic, but gallium nitride dominates that market as an environmental contaminant and photocopiers of and. 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